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By R. Přibil, R. Belcher, H. Freiser

Analytical purposes of EDTA and comparable Compounds examines the analytical functions of ethylenediaminetetra-acetic acid (EDTA) and comparable compounds. This publication additionally considers the “passive” function of those elements, that's, their screening (masking) homes, which significantly increase the selectivity of the reactions in universal use.
This textual content comprises six chapters geared up into sections. the 1st half offers with the makes use of of EDTA and its derivatives in a few fields of chemical research. After delivering an outline of the background in the back of the advance of EDTA as an analytical reagent, this e-book discusses to the character of equilibria of complexes and the tools utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions via natural reagents. The bankruptcy on colorimetry incorporates a part on “colored complexing agents,” which are used additionally in colorimetric determinations of a few parts. this article concludes by means of comparing using EDTA as a overlaying agent in colorimetry.
This publication might be of curiosity to scholars and practitioners operating in analytical chemistry and comparable disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.

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Brit. Patent 4 9 6 , 7 8 1 . 4 2 . U . S . Patent 2 , 4 0 7 , 6 4 5 . 4 3 . U . S . Patent 2 , 1 0 3 , 5 0 5 . 4 4 . SCHWARZENBACH, G . and ACKERMANN, H . , Hel^. chim. acta 3 0 , 1 7 9 9 ( 1 9 4 7 ) . 4 5 . CHAPMAN, D . , / . Chem. Soc. 1 9 5 5 , 1 7 6 6 . 4 6 . PECSOK, R . L . , / . Chem. Educ. 29, 5 9 7 ( 1 9 5 2 ) . 4 7 . BR»iTznsiGER, Η . and HESSE, G . , Z . anorg. Chem. 2 4 9 , 1 1 3 ( 1 9 4 2 ) . 4 8 . BRWÍTZINGER, H . , THIELE, H . and MÍÍLLER, U . , Z . anorg. chem. 2 5 1 , 2 8 5 ( 1 9 4 3 ) .

The proportion of the protonated complex, an intermediate product in M Y complex formation, is given as a function of p H in Fig. 12. e. equilibrium (F) is displaced far to the right, so that the described method cannot be used to determine the stability constant of M Y . The constant for protonated complex formation (CrHY, C o H Y B r " , F e H Y " [6, 52]) can still be determined from the titration curves of these complexes. The curves also show that an M Y O H type hydroxo complex will form in the p H range 5-9 in the case of F e " ^ F e " , C r " ^ Al and M n ' " [52].

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